By Lanny S. Liebeskind
Advances in Metal-Organic Chemistry: A learn Annual, quantity 2 provides the virtues of metal-oriented natural chemistry using stoichiometric and catalytic reagents. This ebook discusses of worth for the synthesis of typically priceless natural structures.
Organized into seven chapters, this quantity starts with an outline of the unreal purposes of chromium tricarbonyl stabilized benzylic carbanions. this article then examines the applying of organometallic complexes to stereoselective natural synthesis. different chapters think of the carbine addition response that has been proven to be worthy in lots of circumstances, yet problems come up as a result inherently excessive reactivity of those species. This booklet discusses besides the most typical substituted-arene complexes, quite these of benzaldehyde and benzoic acid which are reliable whilst ready by way of oblique routes through acetals or esters. the ultimate bankruptcy bargains with the effective ring homologation method for cyclic alkenes.
This e-book is a useful source for man made natural chemists and organometallic chemists.
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Advances in Metal-Organic Chemistry: A Research Annual: 2 by Lanny S. Liebeskind